Abstract

A perovskite precursor solution that delivers power conversion efficiencies (PCEs) exceeding 26% in conventional nip solar cells exhibits severe performance losses when directly applied to inverted pin architectures, revealing that high-efficiency compositions are not inherently transferable. Here, we identify a buried-interface crystallization mismatch, arising from the distinct physicochemical natures of inorganic SnO2 electron-transporting layers and organic self-assembled hole-transporting monolayers (SA-HTLs), as the origin of this divergence. The methylammonium chloride (MACl)-associated intermediate phase, MA2Pb3I8·2DMSO, persists and decomposes with strong underlayer dependence, stabilizing beneficially on SnO2 but impeding crystallization on SA-HTLs. To overcome this limitation, we develop a chloride-origin engineering strategy that decouples chloride functionality from volatile organic ammonium species by incorporating low-solubility lead chloride (PbCl2) with strong Pb–Cl coordination. This enables controlled interfacial desolvation and nucleation on SA-HTLs, suppresses buried defects, and establishes buried-interface crystallization control as a design principle for architecture-convergent, high-efficiency perovskite solar cells.

Building a high-performance solar cell takes more than getting the materials right. The same ingredients can produce very different results when the layers are arranged differently—and researchers at UNIST have discovered why.

Led by Distinguished Professor Sang Il Seok of the School of Energy and Chemical Engineering at UNIST, the team found that the surface beneath the light-absorbing perovskite layer can determine how well its crystals form. By tailoring the material chemistry to that surface, the researchers developed an inverted perovskite solar cell with a power conversion efficiency of 26.3% and improved stability.

PSCs can be built in conventional nip or inverted pin configurations. Both have reached high efficiencies, but formulations optimized for one do not necessarily perform as well in the other. Inverted cells are particularly important for perovskite–silicon tandem solar cells, where they are commonly used as the top cell.

The researchers found that this performance gap originates at the buried interface, where the perovskite layer forms on the material beneath it. A formulation that achieved efficiencies above 26% in conventional cells lost much of its performance when transferred directly to an inverted design.

The difference came down in part to methylammonium chloride (MACl), an additive used to improve perovskite crystal growth. In conventional cells, an intermediate formed by MACl supports crystallization on the underlying inorganic layer. But on the organic layer used in inverted cells, the intermediate persists longer, disrupting crystal growth and leaving behind voids and defects that can lead to electrical losses.

Rather than removing chloride, the team changed how it was introduced. The researchers reduced the amount of MACl and added a small amount of lead chloride (PbCl2), whose stronger interaction with chloride helped control where and when crystals began to form. This produced a cleaner buried interface with fewer defects.

With the revised formulation, the inverted cells reached a peak efficiency of 26.3% and a fill factor of up to 86.8%, while also showing improved stability. The results demonstrate that controlling how perovskite crystals form at the underlying surface can help high-performance materials work across different solar-cell designs.

“High-efficiency formulations developed for conventional PSCs do not necessarily behave the same way in inverted devices,” said Professor Seok. “By identifying the origin of this performance loss, we established a way to control crystal formation at the buried interface. The findings provide a design direction for developing efficient inverted cells for high-performance perovskite–silicon tandem solar cells.”

Their findings have been published online in Joule  on July 28, 2026. The study was supported by the National Research Foundation of Korea (NRF).

Journal Reference

Jongbeom Kim, Nahye Shin, Chaehoon Jeon,  et al ., “Buried-interface crystallization limits the transferability of high-efficiency perovskite precursor compositions,”  Joule ,(2026).