Abstract

Interest in electrochemical glycerol oxidation reactions (GORs) continues to grow as a promising strategy for hydrogen production. By replacing the oxygen evolution reaction (OER), GOR reduces energy consumption while generating hydrogen at the cathode and value-added formate at the anode, offering techno-economic advantages over conventional water electrolysis. However, its practical implementation is still hindered by reliance on precious metal catalysts and performance losses in scaled-up systems. Here, we synthesized a non-precious CuCo oxide (CCO) electrocatalyst at a tens-of-grams scale through co-precipitation and simple surface treatment. When applied to an anion exchange membrane (AEM) electrolyzer, the modified CuCo oxide achieved 110 mA cm−2 at 1.31 Vcell using a 7 cm2 non-precious GOR anode with 96% formate selectivity. The system was further scaled to a 79 cm2 anode, delivering 3.2 A at 1.31 Vcell. This study demonstrates a practical and economically favorable pathway for scalable hydrogen production via glycerol valorization in AEM electrolyzers. 

A joint research team, led by Professors Ji-Wook Jang, Hankwon Lim, and Hosik Lee from the School of Energy and Chemical Engineering at UNIST, in collaboration with Dr. Juchan Yang from the Energy & Environment Materials Research Division at Korea Institute of Materials Science (KIMS), has announced the development of a high-performance, scalable electrochemical system that transforms waste glycerol—an industrial byproduct of biodiesel production—into hydrogen and value-added chemicals, such as formate.

This innovative system replaces the conventional oxygen evolution reaction (OER) in water electrolysis with glycerol oxidation, resulting in reduced energy consumption and enhanced efficiency. Using a copper-cobalt oxide catalyst, the system a current density of 110 mA/cm² at just 1.31 V, with 96% selectivity for formate. The technology was successfully scaled to a 79 cm² electrode, demonstrating its potential for industrial applications.

This advancement provides a sustainable, cost-effective pathway for large-scale hydrogen production through glycerol valorization. By simultaneously generating hydrogen and valuable chemicals from waste biomass, the approach promises significant reductions in green hydrogen costs and improved resource efficiency. Additionally, integrating energy and chemical manufacturing processes supports global efforts toward carbon neutrality and a sustainable hydrogen economy. Moreover, its scalability and compatibility with continuous operation suggest promising prospects for industrial deployment and further scale-up to megawatt-level systems. 

Juchan Yang, Principal Researcher at KIMS, emphasizes, “This study demonstrates the large-scale synthesis of low-cost, non-precious catalysts and their successful integration into a practical electrolyzer system, marking a significant step toward commercial viability.”

Professor Ji-Wook Jang of UNIST adds, “Transforming biomass waste like glycerol into high-value chemicals and hydrogen not only accelerates carbon neutrality but also offers strategic advantages in building a sustainable hydrogen economy.”

The findings of this research were published online in Joule  (IF: 35.4) on March 18, 2026. The study was supported by the National Research Council of Science & Technology (NST), the Korea Institute of Energy Technology Evaluation and Planning (KETEP), the National Research Foundation of Korea (NRF), and the Korea Institute of Industrial Technology (KEIT).  Core analyzes and computational modeling were conducted using supercomputing resources provided by the Korea Institute of Science and Technology Information (KISTI), with technical support, as well as the synchrotron radiation source at the 6D beamline of the Pohang Accelerator Laboratory.

Journal Reference

Ki-Yong Yoon, Seon Woo Hwang, Hee Yoon Roh et al. , “Commercial-scale glycerol valorization using surface-modified copper cobalt oxide catalyst in high-capacity anion exchange membrane electrolyzer,” Joule , (2026).